ABSTRACT
In the present study, we focused on the impact of lockdown on black carbon (eBC) mass concentrations and their associated radiative implications from 01st March to 30th June 2020, over a semi-arid station, i.e., in the district of Anantapur in Southern India. The mean eBC mass concentration was observed before lockdown (01st–24th March 2020) and during the lockdown (25th March–30th June 2020) period and was about 1.74 ± 0.36 and 1.11 ± 0.14 µg m–3, respectively. The sharp decrease (~35%) of eBC mass concentration observed during the lockdown (LD) period as compared with before lockdown (BLD) period, was mainly due to the reduction of anthropogenic activities and meteorology. Furthermore, during the entire LD period, the net composite forcing at the top of the atmosphere (TOA) and at the surface (SUR) varied from –4.52 to –6.19 Wm–2 and –22.91 to –29.35 Wm–2, respectively, whereas the net forcing in the atmosphere (ATM) varied from 17.27 to 23.16 Wm–2. Interestingly, the amount of energy trapped in the atmosphere due to eBC is 11.19 Wm–2 before LD and 8.56 Wm–2 during LD. It is concluded that eBC contributes almost 43–50% to the composite forcing. As a result, the eBC atmospheric heating rate decreased significantly (25%) when compared to before lockdown days to lockdown days.
ABSTRACT
The World Health Organization (WHO) declared the coronavirus disease of 2019 (COVID-19) as a pandemic due to its widespread global infection. This has resulted in lockdown under different phases in many nations, including India, around the globe. In the present study, we report the impact of aerosols on surface ozone in the context of pre-lockdown (01st - 24th March 2020 (PLD)), lockdown phase1 (25th March to 14th April 2020 (LDP1)), and lockdown phase 2 (15th April to 03rd May 2020 (LDP2)) on clear days at a semi-arid site, Anantapur in southern India using both in situ observations and model simulations. Collocated measurements of surface ozone (O3), aerosol optical depth (AOD), black carbon mass concentration (BC), total columnar ozone (TCO), solar radiation (SR), and ultraviolet radiation (UV-A) data were collected using an Ozone analyzer, MICROTOPS sunphotometer, Ozonometer, Aethalometer, and net radiometer during the study period. The diurnal variations of O3 and BC exhibited an opposite trend during three phases. The concentrations of ozone were ~10.7% higher during LDP1 (44.8 ± 5.2 ppbv) than the PLD (40.5 ± 6.0 ppbv), which mainly due to an unprecedented reduction in NOx emissions leading to a lower O3 titration by NO. The prominent increase in the surface zone during LDP1 is reasonably consistent with the observed photolysis frequencies (j (O1D)) through Tropospheric Ultraviolet and Visible (TUV) model. The results show that a pronounced spectral and temporal variability in the AOD during three lockdown phases is mainly due to distinct aerosol sources. The increase in AOD during LDP2 due to long-range transport can bring large amounts of mineral dust and smoke aerosols from the west Asian region and central India, and which is reasonably consistent with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) air mass back trajectories and Moderate Resolution Imaging Spectroradiometer (MODIS) fire counts analysis over the measurement location. Overall, a drastic reduction in BC concentration (~8.4%) and AOD (10.8%) were observed in the semi-arid area during LDP1 with correspondence to PLD. The columnar aerosol size distributions retrieved from the spectral AODs followed power-law plus unimodal during three phases. The absorption angstrom exponent (AAE) analysis reveals a predominant contribution to the BC from biomass burning activities during the lockdown period over the measurement location.